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P. 20-22 /

Transformative syntheses of fluorinated heterocyclics using a difluorohomopropargylic template

SATORU ARIMITSU**, GERALD B. HAMMOND*
*Corresponding author
University of Louisville, Department of Chemistry, Louisville, Kentucky 40292, USA
** Dept of Chemistry, Kyoto University, Japan

Abstract

gem-Difluorohomopropargyl alcohol is a readilyattainable molecular scaffold that provides easy access tofluorinated propargyl-ethers, -esters, and –amides capableof generating structurally diverse fluorinated heterocycles,such as furans, isochromans, isoquinolines and lactams,using cyclization reactions catalyzed mostly by transitionmetals including Ag, Rh, Ru or Pd.


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